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When the stress is low, more bonds contribute their lifetime to the total time-to-failure of the nanotube, resulting in a flattening of the solid curve, so that the stress versus logarithm of time-to-failure curve is approximately linear. Nonetheless, the data do fall within the range of predications of the current kinetic model. It is realized 352 Polymer nanocomposites that frequency effect, SWNT size effect, and multiple SWNT fractures, may also exercise influence, to various extent, on the lifetime of a SWNT, which could be topics for further studies. 13. Conclusions In this chapter we have addressed several issues concerning strength, interface, and long-term behavior of carbon nanotubes and carbon nanotube reinforced polymeric composites, from mechanics point of view. Although tensile strength of CNTs was experimentally determined and simulated at the molecular level in previous studies, a fundamental understanding of the atomic mechanisms leading to the observed wide statistical distribution is still lacking. In particular, what kind of defects exist in the CNTs from a specific synthetic process, how they are distributed along a CNT, how they interact under applied load, and more importantly, how they can be controlled in synthesis are problems to be addressed in the future. Intricate experiments and modeling at both molecular and microscopic level have been performed to elucidate CNT-polymer interactions at the interface. 13. 5 Time-to-failure of zigzag (18, 0) SWNTs versus applied stress. Only the results of the first six cracking modes are shown. Single-walled carbonnanotubes in epoxy composites 353 The majority of the results seem to suggest that CNT-polymer interfacial strength is much higher than that of conventional micro-fiber reinforced polymeric composites. Despite our very limited current under- standing, there is still a lot of room for clarifying the physics at the CNT- polymer interface. A better understanding on the strength (and weakness) of CNTs and CNT-polymer interface issues enable us to design and create nanocomposites with predictable properties and performance. Single-walled carbonnanotubes in epoxy composites 357 64. CNTs are a type of higher order fullerene and have a seamless cylindrical structure formed by the rolling of a graphene sheet. The transmission electron microscope (TEM) image of a CNT and its atomic structure models are shown in Fig. 14. .

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