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In this reported work, the clay mineral was treated with an M-xylylenediamine hardener, where one amine group was previously converted into a cation in an acetic environment. In a further step, dimerization between DGEBA and the free amine group of the surface modifier was initiated. After evaporation of any water present in the system, the blend was cured with stoichiometric amount of 4- aminophenyl sulfone (DDS). The reaction mechanism is illustrated in Fig. 2. . TEM images of the resulting composite appeared to show a very disordered, exfoliated arrangement of the silicate platelets in the polymer matrix. The physical properties of this new material are yet to be reported. Chen et al. 1 and Wang et al. 2,33 reported another approach of highly exfoliated epoxy nanocomposite synthesis using an organoclay slurry to improve the silicate layer dispersion. In the work by Wang et al. the pristine clay was first swollen in water and than transferred into a clay-acetone slurry, including several steps to separate the water from the slurry. TEM images of these materials revealed a well (disorderly) dispersed nanocomposite structure. A summary of improvement in mechanical properties of epoxy nanocomposites in both the rubbery and the glassy state is reported in this section. Fracture properties It is often stated in the literature35 that toughening of a polymer matrix through incorporation of an additional phase occurs within a specific size range of the reinforcing filler. Hence, the silicate platelets in a fully dispersed (disordered exfoliated) arrangement would nominally be too thin to provide toughening of the polymer matrix. In contrast, the lateral, micron-sized structure of intercalated layered silicate tactoids can provide this toughening, mainly through a crack bridging mechanism and increased fracture surface area. The stress intensity factor, KIC, a common indicator of the fracture properties, of these materials showed significant improvements at layered silicate contents of 3. % in weight and above.

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I always give credit to people who are willing to get things done no matter what the budget or circumstances. Several hair raising moments make me think that this film must have been really scary for it's time 40 years ago. Overall, this is a brilliant film that is very cinematic and relies on traditional but very effective tricks of the trade to make it work. Voyeurism comes with loving cinema (or is it the other way around? and what better way to satisfy this urge than watching a documentary about real people, right. With the advent of digital technology there are many docs being made with digital video. And every once in a while it is a blessing to be able to see a documentary shot on film, and on good old nostalgic 16mm. Not only does it bring back memories of documentaries from the pre-DV era, but also it warms up the screen and makes the characters more personable. The attention to continuity of sound worked and gives us a nicely flowing picture. Most children are shot at eye level, bringing us viewers face to face with them; rather than seeing childrens heads from above: the adult angle. The moments of kids with their families remind us of education as a collective community effort. And prizeful moments like the fear of a kid's first day at school, or fights between two kids, are beautifully documented events that most of us probably have been through in our school years. The almost cinema-verite approach avoids the monotonous talking-head approach that many other documentaries like to use. And kids are always going to be cute, and the filmmakers use that as one of their strengths. So it is worth seeing just for that, to honor the filmmakers who, amidst all endeavours of making a film in a country that lacks resources for local cinema, were able to get things done. But one thing that struck me the most, technically, was the lighting in this film. Using layered structures of fore and backgrounds, for instance a character would be in the foreground sitting in a dark room by the window. He would appear as a dark silhouette, surrounded by a dark room, but in the back ground we see the view from outside the window. They obviously set their light exposures to outside to get the effect, but it is noticeable because of it being used several times. This and many other conscious decisions comment on the abilities of the filmmakers and their wilingness to employ the tricks of the trade, even if local cinema in Chad is very new.

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Studies in Language 12: 51-97. Zubeldia, Larraitz. 2013. ? Non)-determining the Original Speaker: Reportative Particles versus Verbs. Research in Language 11 (2): 103-130. There exists a variety of interactive theoretical accounts that acknowledge the undeniable interference of conceptual structure in the system, but nevertheless these do not coincide in the way in which morphology can affect agreement computations. Through a set of cross-linguistic error-elicitation tasks that will be carried out in two languages that greatly differ in their morphological architecture, i. . English and Spanish, this study intends to ascertain the role of morphology in agreement production and draw theoretical implications that help to solve the conflicting premises proposed by the two theoretical approaches under scrutiny, namely the maximalist model and the constraint satisfaction approach. The main debate has been revolving around the idea of agreement as either a purely syntactic phenomenon - following classic generative views (Bock and Eberhard 1993, Franck et al. 2002, among others); or contrariwise, as an interactive process whereby syntax and semantics both play a crucial role in the implementation of agreement markings, as supported by Vigliocco et al. (1996), Haskell et al. (2010), among others. In the experimental domain, it has been demonstrated that conceptual structure is an undeniable source of information that interferes with agreement operations (vid. Eberhard 1999; Thornton and MacDonald 2003; among others), which in turn reveals that the grammatical encoding of agreement is set within a syntax-semantics interface. However, there exists a variety of interactive theoretical accounts that acknowledge the aforementioned potential semantic interference but nevertheless do not coincide in the way in which morphology can affect agreement computations. Therefore, the point of departure of this piece of research will be based on the concept that the architectural morphology of a language is susceptible to become a relevant constraint which interferes with the agreement system. Therefore, what this preliminary experimental study intends to examine is: how agreement morphology behaves during agreement implementation and to what extent it constitutes a relevant constraint in influencing agreement operations in production. In order to accomplish this purpose, a set of cross-linguistic error-elicitation tasks will be carried out in two languages that greatly differ in their morphological architecture, i.

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Michigan is making its 19th NCAA tournament appearance and first since 2012. The buzz: The Wolverines, 16th in the latest Top Drawer Soccer Top 25, are 1-3-1 against ranked teams, but tied No. 8 Indiana and defeated then-No. 9 Maryland. They are led by first-team All-Big Ten Jack Hallahan, who leads the team with seven goals and seven assists. Forward Francis Atuahene, midfielder Robbie Mertz and defender Marcello Borges all made the Big Ten second team. Atuahene has six goals and two assists and Mertz three goals and three assists. Mohammed Zakyi, ranked the nation's third-best freshman by Top Drawer Soccer, has six goals and four assists. What are the odds: Michigan is favored against a Colgate, which is 11-10-1 and won the first NCAA tournament game in school history with a 2-0 upset of No. 22 Massachusetts. However, the Raiders have not faced nearly the competition the Wolverines have, losing to the only ranked team (Syracuse) they have played. The road figures to become tougher after that for the Wolverines with ninth-ranked Louisville (11-2-4) likely next. On the other side of the bracket is third-ranked Akron (16-3-1). A new study in Translational Psychiatry aimed to do just that: By growing cerebral organoids, or mini brains, derived from the cells of a group of patients with schizophrenia, Michal Stachowiak’s group from the University at Buffalo claimed to be one step closer to understanding the cause of this chronic and severe mental disorder. Schizophrenia is typically understood as an illness that starts in the brain at a very early stage of development. Stachowiak’s researchers sought to test this older hypothesis using the latest technology—growing miniature organs that mimic the real brain at the earliest stages of fetal development. The team used skin cells from one group of adult patients diagnosed with schizophrenia as well as a group of adults who were cognitively unimpaired, and, in a process that involves bathing the cells in nutrients and spinning them through a machine that prevents gravity from flattening them, developed organoids from both groups. Keep up with this story and more by subscribing now After growing the mini brains, Stachowiak ’s group compared the 'schizophrenic organoids' to the controls. Stachowiak’s idea was to zero in on the changes or aberrations that this genetic pathway creates. And, he claims, problems in a genomic pathway known as INFS could lead to some of the physiological changes that are responsible for some of the symptoms of schizophrenia.

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I STILL have chills from that monologue Cersei weaved together. Seriously someone needs to call the criminal minds crew STAT and get them over to the GoT writers room because we have some straight up lunatics working there. Even I didn’t see it coming when Jaime let the Unsullied take Casterly Rock and instead overtook Highgarden. In one swoop the Lannisters took out another enemy in Ollena Tyrell and are now, again, the richest house in the seven kingdoms. I know we love to hate them and hate to love them, but you damn sure have to respect them. And she took that poison without even a second in hesitation. She’s such a boss. Jaime was SHOOK. If any queen got real justice this week it was the Queen of Thorns, getting one last poke. I know everyone is complaining about travel time now. No more are the days of our favorite characters trouncing through he deserts or forests or ice mountains of the north. Now they jump from one spot to another like a worldwide version of whack-a-mole. But HOW IN THE SEVEN HELLS does Euron Greyjoy defeat his niece and nephew somewhere outside of Dragonstone, sail all the way back to Kings Landing for a few butt stuff jokes (fuck yeah), and then ALL THE WAY AROUND THE CONTINENT and catch up with Grey Worm and the Unsullied at the exact same time they get to Casterly Rock. Even though the Unsullied presumably left Dragonstone at the same time as the Greyjoys and the Sand Snakes. She sees him as some barbarian bastard from the north that is calling himself King during the turmoil of her current war. He sees her as some rich girl with a good last name that’s spent zero time in Westeros and is now calling herself queen and playing with petty politics rather than focusing on the true enemy to the North. What Jon should’ve done was bring Lyanna Mormont with him as his negotiator. Dany proceeds to eloquently lay out all of the hardships she’s been through. And our hearts were there with her, but she mistakenly sees Jon’s lack of boasting as him not being through just as many hardships. She’s obviously wrong and Daavos makes sure she knows that.

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Her only redeeming quality is her love for her children but even that is so obsessive it is hard to call it an attribute. Lena Headley does such a fantastic job with the character, because even though she’s done such despicable things I can never really get to a point where I am repulsed by her. Love Margaery. Cersei referring to her as the smirking bitch is so apt. What is so laughable is that Margaery is capable of such kindness (as particularly shown towards Sansa), but Cersei keeps going at Margaery and a granddaughter of Ollena Tyrell does not take attacks lying down. Jon being made Lord Commander and that was a great choice, although I am worried that Stannis won’t take kindly to his offer being refused. Jon Stark and the reclaiming of Winterfell by a Stark would have given me such happy moments (and Roose and Ramsay Bolton losing their heads). I get Jon’s decision though, and really support the idea of distance between him and Mellisandre. Stop being such an idealist and bleeding heart, woman. If it was, Drogo would have still been alive. (not over it). It’s taken the characters two episodes to mostly arrive at their new venues, so hopefully episode three will be more explosive. This was also the week that Game of Thrones returned to our screens. Yes, fans wept and countries across the globe gave up productivity for entertainment. It is entertaining but not overwhelming, slowly easing you back into Westeros. Everything is there: the snooty cloak of royalty she dons like she was born with it, her demanding personality and that quiet desperation because even as a young girl she knew that her fate would always not be in her hands. Like we don’t have enough of it with Melisandre being cray-cray. Jon Snow is there, and as everyone knows, Jon Snow never let’s common sense come in the way of making his intentions and beliefs known. I love that she always has a smart ass comment ready for some fool who would think she is not a Queen. I also like that he has become part of Daeny’s council, not just her bedmate.