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2 The time to reach the stationary flux conditions is called lag-time and it allows us to determine the diffusivity of the system. Alternatively, in the pressure decay methods, a polymer sample and a gas are closed in a constant volume. The pressure decreases in time due to the sorption of the gas into the polymer are monitored. 3 Permeability is so low that, in sorption experiments, large pressure differences and membranes of small thickness have to be employed. These restraints do not apply to condensable vapours or highly permeant gas. In the last case, relaxation processes in the polymer matrix cause changes in the transport behaviour and make the permeability time-dependent. In contrast, only vapours of sufficiently high solubility are suitable for the gravimetric measurements used in the sorption experiments. The authors found that the activation energy of moisture permeation obtained from the sorption experiment is lower than that derived from the permeation measurement. They concluded that the interaction and contribution of the diffusion and solubility parameters show complex transport behaviour in these nanocomposite films. An elegant alternative method to measure sorption into polymers is the Attenuated Total Reflectance Fourier Transform Infrared (ATR-FTIR) method. 9,20 It allows in situ acquisition of the kinetic data and at the same time records the changes that occur in the polymer matrix due to the influence of the diffusant. Effects such as swelling, changes in morphology and polymer solvent interactions can all be simultaneously monitored. To calculate the diffusion coefficients from ATR-FTIR data, the mass uptake equation used in gravimetric diffusion experiments has to be modified to take into account the convolution of the evanescent field with the diffusion profile. 278 Polymer nanocomposites 11. Permeation and diffusionmodels relevant topolymer nanocomposites As reported by several authors and as proved by our studies on the transport behaviour, nanocomposites exhibit substantial improvements in gas and vapour permeability. This phenomenon has traditionally been explained by a tortuous path model where the high aspect ratio platelets acts as physical barrier for diffusion of molecules. 1 In his model Nielsen21 assumed that the filler particles are impermeable to the permeant molecules, and are uniformly and completely dispersed in the polymer. Moreover the plates are oriented parallel to the polymer film surface and the filler has no effect on the mobility of the polymer chains. Figure 11. illustrates the general type of path that molecules must take to get through the polymer.
All personality types were similarly distributed between the sexes. The results of the present study were compared to a previous study of DSM-III diagnoses in chronic pain patients and are discussed in terms of the prevalence of DSM-III diagnoses in the general population. Questions are raised as to the applicability of certain DSM-III diagnoses in. No influence of prenatal MA exposure was observed on nicotine-induced increase in locomotor activity in either male or female rats. In conclusion, males with a history of prenatal MA exposure may be more vulnerable to nicotine addiction due to a decrease in nicotine-induced aversive effects. To explore the relationship between workplace bullying and the attitudes of female nurses toward the safety of their patients. This cross-sectional survey study used convenience sampling. Participants included female nurses from a regional teaching hospital. The research tool was a three-part, structured questionnaire that included a basic personal information datasheet, negative behavior scale, and patient safety attitude scale. The researcher distributed 420 questionnaires and collected 329 valid samples (valid return rate: 78. %). Data were analyzed using SPSS software version 22. . The analysis found that 29. % of the participants had suffered from various degrees of workplace bullying. Based on the results, we suggest that supervisors should take the initiative to care for their nursing staffs and to provide them with training in conflict-oriented skills. Organization managers should set up relevant committee-notification mechanisms that construct the safe working environment necessary to reduce workplace bullying and to enhance the patient safety attitudes of nurses, which will indirectly improve the quality of patient care. In the present study, we used adult female rats and applied a 28 days HFCS feeding model to monitor the estrous cycle and changes in tissue weights and histology. Animals were fed with ad libitum normal chow and (1) 24 hours tap water (Control group), (2) 12 hours HFCS access during dark period and 12 hours tap water (12H group), and (3) 24 hours HFCS only access (24H group). There is no significant change in body weight between control and HFCS-fed animals.
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